Ytterbium Vanadate Nanomaterials: Solid State Fabrication, Characterization and Photocatalytic Degradation of MG Industrial Pollutant Under Visible Light Illumination

Document Type : Research Article

Authors

1 Department of Inorganic Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran

2 Department of Inorganic Chemistry, Faculty of Chemistry, Semnan University, Semnan, Iran

10.22091/jaem.2023.9833.1006

Abstract

Ytterbium Vanadate nanopowders were utilized as a photocatalyst to eliminate contamination color under noticeable light illumination. The primary examination was tested by the FullProf program utilizing a profile coordinating with steady scale factors. The outcomes showed that the examples had a primary ytterbium vanadate structure with a space group of Fd-3m. FESEM pictures showed that the combined ytterbium vanadate particles had mono-molded circle morphologies. Photocatalytic execution of the incorporated nanomaterials was likewise examined for the debasement of poison MG under normal light illumination. The ideal circumstances were gotten by design expert programming. It was observed that the ideal condition was 0.07 mL H2O2, 0.02 g catalyst, 40 min. The yield in the condition was 77 %. The stock volume and concentration of MG were 70 mL and 50 ppm, respectively.

Keywords

Main Subjects

In the current work, the photocatalytic execution of Yb2V2O7 to eliminate toxin dye was prepared. The photocatalytic information showed that the got materials had astounding proficiency for the expulsion of MG from the watery arrangement. The ideal circumstances were gotten by the experimental design program. It was observed that the ideal condition was 0.07 mL H2O2, 0.02 g catalyst, 40 min. The yield in the condition was 77 %.

References

[1] Srivastava S., Sinha R., Roy D., (2004), Toxicological effects of malachite green. Aquatic toxicol. 66: 319-329.
https://doi.org/10.1016/j.aquatox.2003.09.008
[2] Tolia J., Chakraborty M., Murthy Z., (2012), Photocatalytic degradation of malachite green dye using doped and undoped ZnS nanoparticles. Pol. J. Chem. Technol. 14: 16-21.
DOI: https://doi.org/10.2478/v10026-012-0065-6
[3] Chen C., Lu C., Chung Y., Jan J., (2007), UV light induced photodegradation of malachite green on TiO2 nanoparticles. J. Hazard. Mater. 141: 520-528.
https://doi.org/10.1016/j.jhazmat.2006.07.011
[4] Sharma J., Sharma S., Vineet Soni V, (2023). Toxicity of
malachite green on plants and its phytoremediation: A review. Regional Studies in Marine Science. 62, 102911.
https://doi.org/10.1016/j.rsma.2023.102911
[5] Miranzadeh M., Afshari F., Khataei B., Kassaee M., (2020), Adsorption and photocatalytic removal of arsenic from water by a porous and magnetic nanocomposite: Ag/TiO2/Fe3O4@GO. Adv. J. Chem. A. 3: 408-421.
https://doi.org/10.33945/SAMI/AJCA.2020.4.3
[6] Sajjadnejad M., Karimi Abadeh H., (2020), Processing of nanostructured TiO2 and modification of its photocatalytic behavior for methylene blue degradation. Adv. J. Chem. A. 3: 422-431.
https://doi.org/10.33945/SAMI/AJCA.2020.4.4
[7] Hu K.-h., Meng M., (2013), Degradation of malachite green on MoS2/TiO2 nanocomposite.  Asian J. Chem. 25: 5827-5829.
https://doi.org/10.14233/ajchem.2013.OH102
[8] Hamad, H., & Moustafa, M. T. (2023). Optimization study of the adsorption of malachite green removal by MgO nano-composite, nano-bentonite and fungal immobilization on active carbon using response surface methodology and kinetic study. Environmental Sciences Europe, 35(1), 1-37.
https://doi.org/10.1186/s12302-023-00728-1
[9] Bansal P., Bhullar N., Sud D., (2009), Studies on photodegradation of malachite green using TiO2/ZnO photocatalyst. Desalin. Water Treat. 12: 108-113.
https://doi.org/10.5004/dwt.2009.944
[10] Soni H., JI N. K., (2014), UV light induced photocatalytic degradation of malachite GREEN on TiO2 nanoparticles. Int. J. Recent Res. Rev. 7: 10-15.
https://doi.org/10.1016/j.jhazmat.2006.07.011
[11] Sols-Casados D., Escobar-Alarcn L., Fernndez M., Valencia F., (2013), Malachite green degradation in simulated wastewater using Nix : TiO2 thin films. Fuel. 110: 17-22.
https://doi.org/10.1016/j.fuel.2012.10.042
[12] Khezami L., Taha K. K., Ghiloufi I., El Mir L., (2016), Adsorption and photocatalytic degradation of malachite green by vanadium doped zinc oxide nanoparticles. Water Sci. Technol. 73: 881-889.
https://doi.org/10.2166/wst.2015.555
[13] Jo W.-K., Parka G. T., Tayade R. J., (2014), Synergetic effect of adsorption on degradation of malachite green dye under blue LED illumination using spiral-shaped photocatalytic reactor. J. Chem. Technol. Biotechnol. 90: 2280-2289.
https://doi.org/10.1002/jctb.4547
[14] He H-Y., (2015), Photocatalytic degradations of malachite green on magnetically separable Ni1-xCoxFe2O4 nanoparticles synthesized by using a hydrothermal process. Amer. Chem. Sci. J. 6: 58-68.
DOI: https://doi.org/10.9734/ACSj/2015/14764
[15] Afshar S., Samari Jahromi H., Jafari N., Ahmadi Z., Hakamizadeh M., (2011), Degradation of malachite green oxalate by UV and visible lights illumination using Pt/TiO2/SiO2 nanophotocatalyst. Sci. Iran. 18: 772-779.
https://doi.org/10.1016/j.scient.2011.06.007
[16] Khademinia S., Behzad M., Kafi-Ahmadi L., Hadilou S., (2018), Hydrothermally synthesized strontium arsenate nanomaterial through response surface methodology. Z. Anorg. Allg. Chem. 644: 221-227.
https://doi.org/10.1002/zaac.201800004
[17] Hosseiny Davarani S. S., Rezayati zad Z., Taheri A. R., Rahmatian N., (2017),  Highly selective solid phase extraction and preconcentration of Azathioprine with nano-sized imprinted polymer based on multivariate optimization and its trace determination in biological and pharmaceutical samples. Mater. Sci. Eng. C. 71: 572–583.
https://doi.org/10.1016/j.msec.2016.09.075
[18] Abdollahi F., Taheri A., Shahmari M., (2019), Application of selective solid-phase extraction using a new core-shell-shell magnetic ionimprinted polymer for the analysis of ultra-trace mercury in serum of gallstone patients. Sep. Sci. Technol.
https://doi.org/10.1080/01496395.2019.1651337
[19] Hosseiny Davarani S. S., Rezayati zad Z., Taheri A. R., Rahmatian N., (2017),  Highly selective solid phase extraction and preconcentration of Azathioprine with nano-sized imprinted polymer based on multivariate optimization and its trace determination in biological and pharmaceutical samples. Mater. Sci. Eng. C. 71: 572–583.
https://doi.org/10.1016/j.msec.2016.09.075
[20] Abdollahi F., Taheri A., Shahmari M., (2019), Application of selective solid-phase extraction using a new core-shell-shell magnetic ionimprinted polymer for the analysis of ultra-trace mercury in serum of gallstone patients. Sep. Sci. Technol.
https://doi.org/10.1080/01496395.2019.1651337 .
 
 
 

Files

Share

How to cite

Statistics